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Journal of Multidisciplinary Applied Natural Science

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Scopus CiteScore 2024

4.8

Calculated on 05 May, 2025

SJR 2024

0.31

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Journal of Multidisciplinary Applied Natural Science

##plugins.themes.gdThemes.general.eIssn##: 2774-3047


Vol 6 No 1 (2026) Articles https://doi.org/10.47352/jmans.2774-3047.310

Green Synthesis of AgNPs from Argentometric Waste using Sandoricum koetjape Pericarp Extract: Structural Characterization and Photocatalytic Activity

Mai Anugrahwati Endang Tri Wahyuni Sri Sudiono

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Mai Anugrahwati

https://orcid.org/0000-0001-8031-8702
  • maianugrahwati@mail.ugm.ac.id
  • Department of Chemistry, Universitas Gadjah Mada, Yogyakarta-55281 (Indonesia); Department of Chemistry, Universitas Islam Indonesia, Yogyakarta-55584 (Indonesia)
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Endang Tri Wahyuni

https://orcid.org/0000-0002-0584-0549
  • endang_triw@ugm.ac.id
  • Department of Chemistry, Universitas Gadjah Mada, Yogyakarta-55281 (Indonesia)
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Sri Sudiono

https://orcid.org/0000-0001-5024-7114
  • ssudiono@ugm.ac.id
  • Department of Chemistry, Universitas Gadjah Mada, Yogyakarta-55281 (Indonesia)
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##plugins.themes.gdThemes.publishedIn##: Oktober 04, 2025

[1]
M. Anugrahwati, E. T. Wahyuni, dan S. Sudiono, “Green Synthesis of AgNPs from Argentometric Waste using Sandoricum koetjape Pericarp Extract: Structural Characterization and Photocatalytic Activity”, J. Multidiscip. Appl. Nat. Sci., vol. 6, no. 1, hlm. 91–107, Okt 2025.

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Abstrak

The growing need for sustainable nanomaterial production has driven research into more environmentally friendly synthesis methods. This study presents an innovative approach for the green synthesis of silver nanoparticles (AgNPs) by valorizing argentometric laboratory waste using Sandoricum koetjape (kecapi) fruit pericarp extract as a natural reducing agent. Unlike previous studies that separately investigated the chemical reduction of silver waste or plant-mediated reduction of AgNO₃, this work integrates both approaches. Initially, the synthesis of AgNPs from silver waste was optimized using response surface methodology with central composite design (RSM-CCD) to determine optimal reaction conditions. Then, a comparison was conducted on the resulting AgNP characteristics and performance with one synthesized from AgNO₃ under the same conditions. The optimized waste-derived AgNPs exhibited a crystallite size of 12 nm and an average particle size of 38.41 nm, along with a distinct surface plasmon resonance (SPR) peak at 420 nm, confirming their nanoscale formation. Comprehensive characterization by UV-Vis spectroscopy, Fourier-transform infrared spectroscopy (FTIR), XRD, TEM, and zeta potential analysis verified the nanoparticles' functionalization, stability, and crystallinity. In photocatalytic performance tests, the waste-derived AgNPs achieved 96% degradation of methylene blue, comparable to the AgNO₃-derived counterpart.

Referensi

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